The correct option is (c) 37^0
For explanation I would say: Let the contact force on the block by the surface be F which makes an angle ϴ with the vertical.
The component of F perpendicular to the contact surface is the normal force N and the component of F parallel to the surface is the friction f As the surface is horizontal, N is vertically upward. For vertical equilibrium,
N = mg = (0.400 kg) (10 m/s^2) = 4.0 N.
The frictional force is f = 3.0 N.
tan ϴ = f/N = 3/4
or, ϴ = tan^-1 (3/4) = 37^0.